4-Methylbenzenethiol → 2-[(4-Methylphenyl)thio]acetonitrile

HRID 66767ノート

反応式

HRID 66767 の反応式
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([SH:8])=[CH:4][CH:3]=1.Cl[CH2:10][C:11]#[N:12].C([O-])([O-])=O.[K+].[K+]>CS(C)=O>[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][CH2:10][C:11]#[N:12])=[CH:4][CH:3]=1

参加物

5

反応物 3

HCID 78114-MethylbenzenethiolHCID 7856ChloroacetonitrileHCID 11430Potassium Carbonate

生成物 1

HCID 27997712-[(4-Methylphenyl)thio]acetonitrile

試薬・触媒・溶媒 1

HCID 679Dimethyl Sulfoxide溶媒

実験手順

The compound 4-methylthiophenoxyacetonitrile was prepared by heating 4-methylthiophenol, chloroacetonitrile and anhydrous K2CO3 in DMSO, employing substantially the same procedure described in previous examples.

出典と根拠

ORDレコード
ord-135cec88a4434915a548520ac93a9dd3
出典データセット
uspto-grants-1982_08
特許番号
US04343808

反応ノート

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