Hydrogen Peroxide → 1,2-Epoxycyclooctane

HRID 67042

反応式

HRID 67042 の反応式
OO.Cl[CH2:4][C:5]([C:7](Cl)(Cl)Cl)=[O:6].[CH:11]1[CH2:18][CH2:17]CCC[CH2:13][CH:12]=1.C(Cl)(Cl)Cl>O>[CH:4]12[O:6][CH:5]1[CH2:7][CH2:13][CH2:12][CH2:11][CH2:18][CH2:17]2

参加物

6

反応物 4

HCID 784Hydrogen PeroxideHCID 6212ChloroformHCID 136091-CycloocteneHCID 281882-Propanone, 1,1,1,3-tetrachloro-

生成物 1

HCID 675131,2-Epoxycyclooctane収率 83%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

There were added 13.68 parts of a 50% aqueous hydrogen peroxide to a refluxing mixture of 3.92 parts of tetrachloroacetone, 11.58 parts of cyclooctene and 149 parts of chloroform. Water was removed continuously as it was formed, over a period of 4 hours of heating. The removed water was then added to the reaction mixture. The organic phase was then separated from the aqueous phase. Based on VPC analysis there was obtained an 83% yield of cyclooctene oxide.

後処理

  1. customWater was removed continuously as it
  2. customwas formed, over a period of 4 hours
  3. temperatureof heating
  4. customThe organic phase was then separated from the aqueous phase

出典と根拠

ORDレコード
ord-07e7b8d911554e5d89dde51561daed3a
出典データセット
uspto-grants-1982_08
特許番号
US04344887

関連ノート

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