1,2,4,5-Tetrachlorobenzene → 2,4,5-Trichlorophenol

HRID 67197

反応式

HRID 67197 の反応式
[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[C:5]([Cl:9])=[CH:4][C:3]=1Cl.[OH-:11].[Na+]>>[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[C:5]([Cl:9])=[CH:4][C:3]=1[OH:11]

参加物

3

反応物 2

HCID 72701,2,4,5-TetrachlorobenzeneHCID 14798Sodium Hydroxide2 回

生成物 1

HCID 72712,4,5-Trichlorophenol

実験手順

The presently employed technology to produce 2,4,5-trichlorophenoxyacetic acid (2,4,5-T) and 2,4,5-trichlorophenol (2,4,5-TCP) commercially involves the dechlorination of 1,2,4,5-tetrachlorobenzene with aqueous sodium hydroxide or anhydrous sodium hydroxide in the presence of alcohols under elevated temperatures and pressures to form 2,4,5-TCP according to the reaction: ##STR2## Under the conditions of alkalinity, temperature and pressure, this process produces between 1 to 100 parts per million of the highly toxic teratogen 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) according to the reaction: ##STR3##

出典と根拠

ORDレコード
ord-a5ea598de76f4ad5a088742a46523e79
出典データセット
uspto-grants-1982_08
特許番号
US04345097

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