N-(2-Hydroxyethyl)ethylenediamine → 4-Behenoyloxyethyl-2,3,6,7-tetrahydro-1,4-diazocin-5-one
反応式
[OH:1][CH2:2][CH2:3][NH:4][CH2:5][CH2:6][NH2:7].[CH:8]([CH2:10][CH2:11][C:12]([O:14]C)=O)=O.[C:16](O)(=[O:38])[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37]>>[C:16]([O:1][CH2:2][CH2:3][N:4]1[C:12](=[O:14])[CH2:11][CH2:10][CH:8]=[N:7][CH2:6][CH2:5]1)(=[O:38])[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH3:37]参加物
4
実験手順
Into an apparatus similar to that in Example 1, were charged 104.2 g (1 mole) of N-hydroxyethylethylenediamine and 116.1 g (1 mole) of methyl 3-formylpropionate. At 130° C., 18 g of water and 32 g of methanol were distilled off. After adding 340.5 g (1 mole) of behenic acid, esterification was carried out at 210° to 220° C. to obtain 4-behenoyloxyethyl-2,3,6,7-tetrahydro-1,4-diazocin-5-one.
後処理
- distillationAt 130° C., 18 g of water and 32 g of methanol were distilled off