Butyl iodide → 1-[4-(t-Butyldimethylsilyl)oxy-2,6,6-Trimethylcyclohex-1-enyl]Oct-1-en-3-one

反応式

[Si:1]([O:8][CH:9]1[CH2:14][C:13]([CH3:16])([CH3:15])[C:12]([CH:17]=[CH:18][C:19](=[O:21])[CH3:20])=[C:11]([CH3:22])[CH2:10]1)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2].[CH2:23](I)[CH2:24][CH2:25][CH3:26]>>[Si:1]([O:8][CH:9]1[CH2:14][C:13]([CH3:15])([CH3:16])[C:12]([CH:17]=[CH:18][C:19](=[O:21])[CH2:20][CH2:23][CH2:24][CH2:25][CH3:26])=[C:11]([CH3:22])[CH2:10]1)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2]

参加物

反応物 2

HCID 10962Butyl iodide

HCID 541718584-[4-(t-Butyldimethylsilyl)oxy-2,6,6-trimethylcyclohex-1-enyl]but-3-en-2-one

生成物 1

HCID 540453681-[4-(t-Butyldimethylsilyl)oxy-2,6,6-Trimethylcyclohex-1-enyl]Oct-1-en-3-one

実験手順

The entitled compound was prepared from 4-[4-(t-butyldimethylsilyl)oxy-2,6,6-trimethylcyclohex-1enyl]but-3-en-2-one and n-butyl iodide in the same manner as described in Example 2-(1).

出典と根拠

ORDレコード: ord-de53e0d1092349e1bac5382b617d102e
出典データセット: uspto-grants-1991_01
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04983723

反応ノート

読み込み中…