Cyanuric chloride → 1,3,5-Triazine, 2,4,6-tris(1-azetidinyl)-

HRID 704114ノート

反応式

HRID 704114 の反応式
[NH:1]1[CH2:4][CH2:3][CH2:2]1.[N:5]1[C:12](Cl)=[N:11][C:9](Cl)=[N:8][C:6]=1Cl>O>[N:1]1([C:6]2[N:8]=[C:9]([N:1]3[CH2:4][CH2:3][CH2:2]3)[N:11]=[C:12]([N:1]3[CH2:4][CH2:3][CH2:2]3)[N:5]=2)[CH2:4][CH2:3][CH2:2]1

参加物

4

反応物 2

HCID 7954Cyanuric chlorideHCID 10422Azetidine

生成物 1

HCID 1520761,3,5-Triazine, 2,4,6-tris(1-azetidinyl)-収率 78%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

Compound LXXVI was prepared after the method of Schaefer (J Am Chem Soc (1955) 77 p592B). The hydrochloride salt of azetidine was reacted with cyanuric chloride in water to give compound LXXVI as a white solid (yield 78%) having a melting point of 225°-238° C. The 1Hnmr of this compound indicated that its identity was correct and that its purity was adequate for subsequent reactions without further purification.

後処理

  1. customCompound LXXVI was prepared after the method of Schaefer (J Am Chem Soc (1955) 77 p592B)

出典と根拠

ORDレコード
ord-5e35f850284549238e6e160ccc3f5f5b
出典データセット
uspto-grants-1991_01
特許番号
US04985584

反応ノート

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