関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Octane | HCID 356 | — |
| 反応物 | Azobisisobutyronitrile | HCID 6547 | — |
| 反応物 | Styrene | HCID 7501 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | Styrene | HCID 7501 | — |
| 生成物 | p-Divinylbenzene | HCID 66041 | — |
反応手順
1 g of the amphiphilic macromolecule reversible addition-fragmentation chain transfer agent and 80 g of deionized water were formulated into an aqueous solution as an aqueous phase, which was added and uniformly mixed with an oil phase consisting of 6 g of styrene, 12 g of p-vinyl benzene, 0.1 g of azobisisobutyronitrile and 9 g of n-octane, and prepared by an ultrasonic crasher into a miniemulsion under the effect of a high shear field. The miniemulsion was transferred to a reactor and subjected to the reaction at a temperature of 80° C. which stopped after 4 hours, and then cooled to the room temperature and discharged to yield polymeric nanocapsules with highly crosslinked shells which were formed by the polymerization of styrene and p-divinyl benzene, wherein the polymeric nanocapsules have an average diameter of 90 nm.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 特許番号 | US09180486B2 |
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| 出典データセット | uspto-grants-2015_11 |
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| ORD ID | ord-2e2acda0e6dc42248c0d402693e5079b |
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| 出典メモ | uspto-grants-2015_11 |
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