1-Butanol → Zirconium butoxide

HRID 727988ノート

反応式

HRID 727988 の反応式
[CH2:1]([OH:5])[CH2:2][CH2:3][CH3:4].[Zr:6].O>C(O)CC.CC(O)C>[CH3:4][CH2:3][CH2:2][CH2:1][O-:5].[CH3:4][CH2:3][CH2:2][CH2:1][O-:5].[CH3:4][CH2:3][CH2:2][CH2:1][O-:5].[CH3:4][CH2:3][CH2:2][CH2:1][O-:5].[Zr+4:6]

参加物

6

反応物 3

HCID 2631-ButanolHCID 962WaterHCID 23995Zirconium

生成物 1

HCID 160560Zirconium butoxide

試薬・触媒・溶媒 2

HCID 10311-Propanol溶媒2 回HCID 3776Isopropanol溶媒

実験手順

1 butanol (171.6 gm) was mixed with 125 ml of n-propanol and placed in a one liter, three-neck round-bottom flask under nitrogen atmosphere. The concentration of zirconium was 0.95 molar. A solution of 28.8 ml of deionized water in 125 ml of n-propanol was added through an addition funnel under nitrogen atmosphere to the solution in the flask with rapid stirring for two minutes. The stirring was stopped, and the mixture was left to stand for three hours. The mixture was then centrifuged, and the mother liquor was discarded. The solid residue was ultrasonically dispersed in 2-propanol and then centrifuged to harvest the supernatant sol. This procedure was repeated several times.

後処理

  1. waitthe mixture was left
  2. waitto stand for three hours

出典と根拠

ORDレコード
ord-86d93c301391450cb70c8a9187b58abc
出典データセット
uspto-grants-1991_09
特許番号
US05047174

反応ノート

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