Toluene → tert-Butylacrylamide
反応式
C([C:5](=[CH2:9])[C:6]([NH2:8])=[O:7])(C)(C)C.[C:10]1([CH3:16])[CH:15]=CC=C[CH:11]=1.N(C(C)(C)C#N)=NC(C)(C)C#N>CCCCCC>[C:10]([NH:8][C:6](=[O:7])[CH:5]=[CH2:9])([CH3:16])([CH3:15])[CH3:11]参加物
5
反応条件
- 温度
- 80 °C
実験手順
A mixture of 50.0 g of t-butylacrylamide and 250 ml of toluene was heated at 80° C. with stirring under a nitrogen atmosphere in a 500 ml three-necked flask. 10 ml of a toluene solution containing 500 mg of azobisisobutyronitrile was added thereto as a polymerization initiator, whereby polymerization was initiated. After polymerization for 3 hours, the polymerization solution was cooled and poured into 1 liter of hexane. The solids thus-deposited were collected by filtration, washed with hexane and dried with heating under a reduced pressure to obtain 47.9 g of P-57.
後処理
- additionwas added
- customas a polymerization initiator, whereby polymerization
- customAfter polymerization for 3 hours
- temperaturethe polymerization solution was cooled
- filtrationThe solids thus-deposited were collected by filtration
- washwashed with hexane
- customdried
- temperaturewith heating under a reduced pressure
出典と根拠
- ORDレコード
- ord-9d56201c1e6b437a8b93522421836aa8
- 出典データセット
- uspto-grants-1991_09
- 特許番号
- US05047314
反応ノート
読み込み中…