反応式
[O-2].[Cd+2:2].[CH2:3]([C:17]([OH:19])=[O:18])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]>>[CH2:3]([C:17]([O-:19])=[O:18])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].[Cd+2:2].[CH2:3]([C:17]([O-:19])=[O:18])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]参加物
3
反応条件
- 温度
- 90 °C
実験手順
Cadmium oxide (0.127 g, 1 mmol) and tetradecylcarboxylic acid (0.500 g) were reacted at 220° C. for 10 min, cooled to 90° C., then a cadmium tetradecylcarboxylate (precursor) was formed. Into said system, toluene (10 ml), trioctylphosphine oxide (3.866 g) and trioctylphosphine (3.7 g) were added. Then a 0.05M aqueous solution of sodium hydrogen selenide (10 ml) was added. After the system was reacted at 90° C. for 3 h, a clear red sol containing the CdSe nanoparticles was obtained. Said sol has a typical exciton absorption peak of CdSe nanoparticle, can result in a quantum size effect and emit a fairly strong green light under the irradiation of a UV lamp.
出典と根拠
- ORDレコード
- ord-ad8319f307bd462cb6596250f2093f91
- 出典データセット
- uspto-grants-2009_09
- 特許番号
- US07582543B2
関連ノート
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