2,2,3,3,3-Pentafluoropropanol → 2,2,3,3,3-Pentafluoropropyl trifluoromethanesulfonate

HRID 733288

反応式

HRID 733288 の反応式
FC(F)(F)S([O:6][S:7]([C:10]([F:13])([F:12])[F:11])(=[O:9])=[O:8])(=O)=O.[F:16][C:17]([F:24])([C:20]([F:23])([F:22])[F:21])[CH2:18]O>>[F:13][C:10]([F:11])([F:12])[S:7]([O:6][CH2:18][C:17]([F:24])([F:16])[C:20]([F:23])([F:22])[F:21])(=[O:8])=[O:9]

参加物

3

反応物 2

HCID 98722,2,3,3,3-PentafluoropropanolHCID 67749Trifluoromethanesulfonic anhydride

生成物 1

HCID 27760192,2,3,3,3-Pentafluoropropyl trifluoromethanesulfonate収率 97%

反応条件

温度
90 °C

実験手順

A mixture of trifluoromethanesulfonic anhydride (40 mL, 0.24 mol) and 2,2,3,3,3-pentafluoropropanol (25 mL, 0.24 mol) was heated under argon at 90° C. overnight. Then, the crude mixture was distilled at atmospheric pressure to give the desired product as a colourless oil (97% yield).

後処理

  1. distillationThen, the crude mixture was distilled at atmospheric pressure

出典と根拠

ORDレコード
ord-5c7fcfdc30414347a5f208e1333ccbe4
出典データセット
uspto-grants-2009_09
特許番号
US07589125B2

関連ノート

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