Hydrochloric Acid → Lytron 810

HRID 742512

反応式

HRID 742512 の反応式
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.C([Al](CC(C)C)CC(C)C)C(C)C.[C:22]1(=[O:28])[O:27][C:25](=[O:26])[CH:24]=[CH:23]1.Cl>C1(C)C=CC=CC=1.C[O-].C[O-].C[O-].CC1([Ti+3])C(C)=C(C)C(C)=C1C.CO>[C:25]1(=[O:26])[O:27][C:22](=[O:28])[CH:23]=[CH:24]1.[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

参加物

8

反応物 4

HCID 313Hydrochloric AcidHCID 7501StyreneHCID 7923Maleic AnhydrideHCID 16682931Triisobutylaluminum

生成物 1

HCID 62707Lytron 810

試薬・触媒・溶媒 3

HCID 178425991HCID 178425991、化合物触媒HCID 887Methanol溶媒HCID 1140Toluene溶媒2 回

実験手順

Into a dried 4 liter stainless steel-made autoclave were introduced 630 ml of toluene, 1.2 liter of styrene, 24 mmol of triisobutylaluminum and 24 mmol of methylaluminoxane which was prepared in Example at 70° C. with stirring for 30 minutes. To the resultant mixture was added 120 μmol of 1,2,3,4,5-pentamethylcyclopentadienyl titanium trimethoxide to initiate polymerization. After an elapse of 50 minutes, a solution of 260 mmol of maleic anhydride in 360 ml of toluene was added to the mixture to continue polymerization for 60 minutes. After the completion of the reaction, the resultant polymer was taken out from the autoclave, deashed with a mixed solution of hydrochloric acid and methanol, washed with methanol for the purification thereof and dried to afford 570 g of copolymer.

後処理

  1. customwas prepared in Example at 70° C.
  2. custompolymerization
  3. custompolymerization for 60 minutes
  4. customAfter the completion of the reaction
  5. washwashed with methanol for the purification
  6. customdried

出典と根拠

ORDレコード
ord-26012d10553d45ccbc21032ba0f486a3
出典データセット
uspto-grants-1996_09
特許番号
US05554695

関連ノート

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