Sodium Azide → Pentanitrophenyl azide
反応式
[N+:1]([C:4]1[C:9]([N+:10]([O-])=O)=[C:8]([N+:13]([O-:15])=[O:14])[C:7]([N+:16]([O-:18])=[O:17])=[C:6]([N+:19]([O-:21])=[O:20])[C:5]=1[N+:22]([O-:24])=[O:23])([O-:3])=[O:2].[N-:25]=[N+:26]=[N-].[Na+]>C1C=CC=CC=1>[N+:1]([C:4]1[C:9]([N:10]=[N+:25]=[N-:26])=[C:8]([N+:13]([O-:15])=[O:14])[C:7]([N+:16]([O-:18])=[O:17])=[C:6]([N+:19]([O-:21])=[O:20])[C:5]=1[N+:22]([O-:24])=[O:23])([O-:3])=[O:2]参加物
4
実験手順
The reaction is conducted by stirring a benzene solution of hexanitrobenzene with a slight excess of sodium azide (aqueous solution) at 25° C. After separating and drying the benzene solution, the solvent is removed leaving pure pentanitrophenyl azide. Recrystallization from carbon tetrachloride gives either long, flat yellow prisms (α-form) or chunky, orange-yellow rosettes (β-form) of pentanitrophenyl azide.