Bis(2-ethylhexyl) phosphate → Potassium bis(2-ethylhexyl) phosphate

HRID 747828

反応式

HRID 747828 の反応式
[K].[P:2]([OH:22])([O:13][CH2:14][CH:15]([CH2:20][CH3:21])[CH2:16][CH2:17][CH2:18][CH3:19])([O:4][CH2:5][CH:6]([CH2:11][CH3:12])[CH2:7][CH2:8][CH2:9][CH3:10])=[O:3].[H-].[K+:24].[OH-].[K+]>CCCCCCC>[CH2:11]([CH:6]([CH2:7][CH2:8][CH2:9][CH3:10])[CH2:5][O:4][P:2]([O-:22])([O:13][CH2:14][CH:15]([CH2:20][CH3:21])[CH2:16][CH2:17][CH2:18][CH3:19])=[O:3])[CH3:12].[K+:24]

参加物

6

反応物 4

HCID 9275Bis(2-ethylhexyl) phosphate2 回HCID 14797Potassium Hydroxide2 回HCID 82127Potassium hydrideHCID 5462222Potassium

生成物 1

HCID 23675922Potassium bis(2-ethylhexyl) phosphate

試薬・触媒・溶媒 1

HCID 8900Heptane溶媒2 回

実験手順

The potassium salt of bis(2-ethylhexyl) hydrogen phosphate was made by the direct reaction of potassium hydride with the corresponding acid in heptane. The acid bis(2-ethylhexyl) hydrogen phosphate (Aldrich Chemicals; 64.49 grams or 0.2 moles) was placed in 300 ml of dry heptane and stirred gently. An excess of potassium hydroxide granules was added to the solution and left to stir until no further potassium hydroxide reacted. At completion the reaction solution was decanted and the heptane evaporated to leave the potassium bis(2-ethylhexyl) phosphate salt as a white waxy solid.

後処理

  1. waitleft
  2. customreacted
  3. customAt completion the reaction solution was decanted
  4. customthe heptane evaporated

出典と根拠

ORDレコード
ord-b4bd8634624845dba2efd597a5be4759
出典データセット
uspto-grants-2008_07
特許番号
US07399731B2

関連ノート

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