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Hydrochloric Acid → HCl MTBD
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydrochloric Acid | HCID 313 | — |
| 反応物 | 7-Methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene | HCID 123583 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | HCl MTBD | HCID 131730803 | — |
反応手順
A flame dried flask was charged with MTBD (0.25 g, 1.63 mmol), ether (10 mL) and a stirbar under dry nitrogen atmosphere. With vigorous stirring a 1M ethereal HCl solution (1.6 mL) was then added to form a white precipitate. Stirring was continued for 1 hour then excess solvent was decanted to yield 0.29 g (94%). The salt was then dried under high vacuum.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08846851B2 |
| 出典データセット | uspto-grants-2014_09 |
| ORD ID | ord-e12c52601aad40bdbaaefe1cc77a32ec |
| 出典メモ | uspto-grants-2014_09 |