Benzene → HCID 86664985、化合物

HRID 83957

反応式

HRID 83957 の反応式
[CH2:1]=[C:2]1[CH2:7][CH:6]([CH3:8])[O:5][C:3]1=[O:4].C1C=CC=CC=1.[CH:15]([C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=1[CH:23]=[CH2:24])=[CH2:16]>>[CH2:1]=[C:2]1[CH2:7][CH:6]([CH3:8])[O:5][C:3]1=[O:4].[CH:15]([C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][C:18]=1[CH:23]=[CH2:24])=[CH2:16]

参加物

4

反応物 3

HCID 241BenzeneHCID 666661,2-DiethenylbenzeneHCID 99939gamma-Methyl-alpha-methylene-gamma-butyrolactone

生成物 1

HCID 86664985HCID 86664985、化合物

反応条件

温度
65 °C

実験手順

To a dry 100 mL round bottom flask equipped with a magnetic stir bar was charged 1.0153 g (8.98×10−3 mol) α-methylene-γ-valerolactone, 16.78 g (0.215 mol) benzene, 0.0561 g (4.31×10−4 mol) divinyl benzene, and 0.0067 g (4.08×10−5 mol) azobisisobutylnitrile. The reactor was purged with nitrogen for 30 minutes before heating to 65° C. The reactor was held at 65° C. for 5 hours before letting cooling the reaction mixture to room temperature and drying under vacuum.

後処理

  1. customTo a dry 100 mL round bottom flask equipped with a magnetic stir bar
  2. customThe reactor was purged with nitrogen for 30 minutes
  3. temperaturebefore letting cooling the reaction mixture to room temperature
  4. customdrying under vacuum

出典と根拠

ORDレコード
ord-cc45147e8cd34e0daca082f656717305
出典データセット
uspto-grants-2014_09
特許番号
US08846817B2

関連ノート

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