m-Chloroperbenzoic acid → 86088-36-0
反応式
[C:1]1([CH2:7][CH2:8][CH2:9][CH:10]=[CH2:11])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.ClC1C=CC=C(C(OO)=[O:20])C=1>ClCCl>[C:1]1([CH2:7][CH2:8][CH2:9][CH:10]2[CH2:11][O:20]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1参加物
4
実験手順
5-Phenylpent-1-ene (14.2 g, 0.0973 mol) and m-chloroperbenzoic acid (16.79 g, 0.0973 mol) in dichloromethane (300 ml) was stirred at room temperature for 4 hours. The solution was washed with saturated aqueous sodium hydrogen carbonate solution and dried (MgSO4). The solvent was evaporated off under reduced pressure to give an oil which was distilled to give 2-(3-phenylpropyl)oxirane (b.p. 85° C., 0.4 mm.Hg).
後処理
- washThe solution was washed with saturated aqueous sodium hydrogen carbonate solution
- dry with materialdried (MgSO4)
- customThe solvent was evaporated off under reduced pressure
- customto give an oil which
- distillationwas distilled
出典と根拠
- ORDレコード
- ord-856ecebd459747f7a1f60cfa605108ea
- 出典データセット
- uspto-grants-1988_07
- 特許番号
- US04758573
反応ノート
読み込み中…