1,1'-Biphenyl, mixt. with 1,1'-oxybis(benzene) → Quinacridone

HRID 845559

反応式

HRID 845559 の反応式
[NH:1]([C:8]1[CH2:17][C:16]([C:18]([O:20]C)=O)=[C:15]([NH:22][C:23]2[CH:28]=[CH:27][CH:26]=[CH:25][CH:24]=2)[CH2:14][C:9]=1[C:10]([O:12]C)=O)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C1C=CC(C2C=CC=CC=2)=CC=1.C1C=CC(OC2C=CC=CC=2)=CC=1>>[CH:26]1[CH:27]=[C:28]2[C:18]([C:16]3[C:15]([NH:22][C:23]2=[CH:24][CH:25]=1)=[CH:14][C:9]1[C:10]([C:7]2[C:2]([NH:1][C:8]=1[CH:17]=3)=[CH:3][CH:4]=[CH:5][CH:6]=2)=[O:12])=[O:20]

参加物

3

反応物 2

HCID 246701,1'-Biphenyl, mixt. with 1,1'-oxybis(benzene)2 回HCID 786101,4-Cyclohexadiene-1,4-dicarboxylic acid, 2,5-bis(phenylamino)-, 1,4-dimethyl ester

生成物 1

HCID 13976Quinacridone収率 89%

反応条件

温度
140 °C

実験手順

(b.1) A suspension of 37.8 parts of dimethyl 3,6-dihydro-2,5-dianilinoterephthalate in 200 parts of ®Dowtherm A is added dropwise to 150 parts of boiling ®Dowtherm A. The mixture is then kept at the boil for a further 90 minutes. After approx. 100 parts of the solvent have been distilled off, the mixture is cooled to approx. 140° C., after which 25.4 parts of iodine are added and the mixture is kept at the boil for a further 4 hours. Working up is effected as described earlier in the text under "Method A". 27.8 parts of quinacridone in the β-crystal phase are obtained, which corresponds to a yield of 89% of theory (relative to dimethyl 3,6-dihydro-2,5-dianilinoterephthalate.

後処理

  1. additionis added dropwise to 150 parts
  2. distillationhave been distilled off
  3. additionafter which 25.4 parts of iodine are added
  4. waitthe mixture is kept at the boil for a further 4 hours

出典と根拠

ORDレコード
ord-3d8f5738a72c47d997233d9b488f6ece
出典データセット
uspto-grants-1988_07
特許番号
US04758664

関連ノート

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