化工社化工社 化学情報印刷レポート · 研究参考用
1-Dodecanethiol → Ethyl Acrylate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Dodecanethiol | HCID 8195 | — |
| 反応物 | Tert-butyl 2-ethyl-2-methylheptaneperoxoate | HCID 71359725 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | Ethyl Acrylate | HCID 8821 | — |
| 生成物 | Decyl methacrylate | HCID 18510 | — |
反応手順
350 g of toluene, 135 g of ethyl acrylate, and 15 g of n-decyl methacrylate were polymerized with stirring in a reaction flask at 50°-60° C. under argon with 0.3 g of dodecyl mercaptan as a regulator and 2 g of t-butyl perneodecanoate as initiator. After about 30 minutes of reaction, the mixture was precipitated in methanol and the polymer was dried under vacuum.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05141993 |
| 出典データセット | uspto-grants-1992_08 |
| ORD ID | ord-c2b49c75adc9482d84cd3eef32fdd950 |
| 出典メモ | uspto-grants-1992_08 |