Lithium Hexamethyldisilazide → Chromium tris(bis(trimethylsilyl)amide)

反応式

[Cl-].[Cl-].[Cl-].[Cr+3:4].[CH3:5][Si:6]([N-:9][Si:10]([CH3:13])([CH3:12])[CH3:11])([CH3:8])[CH3:7].[Li+]>>[CH3:5][Si:6]([N-:9][Si:10]([CH3:13])([CH3:12])[CH3:11])([CH3:8])[CH3:7].[CH3:5][Si:6]([N-:9][Si:10]([CH3:13])([CH3:12])[CH3:11])([CH3:8])[CH3:7].[CH3:5][Si:6]([N-:9][Si:10]([CH3:13])([CH3:12])[CH3:11])([CH3:8])[CH3:7].[Cr+3:4]

参加物

反応物 2

HCID 2733832Lithium Hexamethyldisilazide

HCID 6452300Chromium(3+) trichloride

生成物 1

HCID 6097019Chromium tris(bis(trimethylsilyl)amide)

実験手順

In accordance with the method disclosed in J. Chem. Soc. (A), 1433 (1971), chromium (III) tris(bistrimethylsilylamide) was synthesized by reaction of anhydrous chromium trichloride anhalide with lithiumbistrimethylsilylamide.

出典と根拠

ORDレコード: ord-d49c44fa511d42d099ae63133ff923c7
出典データセット: uspto-grants-2000_01
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06011127

反応ノート

読み込み中…