Thionyl Chloride → 2-Acetylthiomethyl-3-phenyl-propionyl chloride

反応式

[C:1]([S:4][CH2:5][C@@H:6]([CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)[C:7](O)=[O:8])(=[O:3])[CH3:2].S(Cl)([Cl:19])=O>>[C:1]([S:4][CH2:5][CH:6]([CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)[C:7]([Cl:19])=[O:8])(=[O:3])[CH3:2]

参加物

反応物 2

HCID 24386Thionyl Chloride

HCID 7408367HCID 7408367、化合物

生成物 1

HCID 103777342-Acetylthiomethyl-3-phenyl-propionyl chloride

実験手順

(S)-2-Acetylthiomethyl-3-phenylpropanoic acid (Ia S) (Example 2, stage e) is treated with thionyl chloride according to the same procedure as that described in Example 3, stage f.

出典と根拠

ORDレコード: ord-a0add61c53bb4480a5789a3d1f78f0ab
出典データセット: uspto-grants-2000_01
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US06013829

反応ノート

読み込み中…