Methane → 4-Tetradecylbenzenediazonium nitrate

HRID 861182ノート

反応式

HRID 861182 の反応式
C.C1C(Br)=C(Br)[NH:4]C=1C(O)=O.N([O-])=O.[Na+].[CH2:16]([C:30]1[CH:36]=[CH:35][C:33]([NH2:34])=[CH:32][CH:31]=1)[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29].[N+:37]([O-:40])([OH:39])=[O:38]>O.CC(C)=O>[N+:37]([O-:40])([O-:39])=[O:38].[CH2:16]([C:30]1[CH:31]=[CH:32][C:33]([N+:34]#[N:4])=[CH:35][CH:36]=1)[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH3:29]

参加物

8

反応物 5

HCID 297Methane2 回HCID 944Nitric AcidHCID 145224p-TetradecylanilineHCID 1618304,5-Dibromo-2-Pyrrolic AcidHCID 23668193Sodium Nitrite

生成物 1

HCID 197024474-Tetradecylbenzenediazonium nitrate

試薬・触媒・溶媒 2

HCID 180Acetone溶媒HCID 962Water溶媒3 回

実験手順

A carbon black with a surface area of 58 m2 /g and a DBPA of 46 ml/100 g was used. A suspension of 50 g of this carbon black was prepared by stirring it into 450 g of water. A solution of 0.85 g of NaNO2 in 4 g of cold water was slowly added to a dispersion of 2.98 g of 4-tetradecylaniline, 1.98 g of concentrated nitric acid and 4 ml of acetone in 15 g of water that was cooled in an ice bath. 4-Tetradecylbenzenediazonium nitrate was formed. After 15 minutes of stirring, the mixture was added to the stirring carbon black suspension. Bubbles were released. After 30 minutes, the product was collected by filtration, washed with water and tetrahydrofuran (THF) and dried in an oven at 125° C. The carbon black product had attached p-C6 H4C14H29 groups.

後処理

  1. customwas prepared
  2. temperaturewas cooled in an ice bath

出典と根拠

ORDレコード
ord-f7cbdd8d4b9c46aa8b4db7a1f2400d52
出典データセット
uspto-grants-1998_02
特許番号
US05713988

反応ノート

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