1,4-Dichlorobenzo[g]phthalazine → HCID 19699649、化合物
反応式
[Cl:1][C:2]1[C:11]2[CH:10]=[C:9]3[CH:12]=[CH:13][CH:14]=[CH:15][C:8]3=[CH:7][C:6]=2[C:5](Cl)=[N:4][N:3]=1>C(N)CCC>[ClH:1].[CH2:2]([NH:3][C:2]1[C:11]2[CH:10]=[C:9]3[CH:12]=[CH:13][CH:14]=[CH:15][C:8]3=[CH:7][C:6]=2[C:5]([NH:4][CH2:5][CH2:6][CH2:7][CH3:8])=[N:4][N:3]=1)[CH2:11][CH2:10][CH3:9]参加物
3
反応条件
- 温度
- 130 °C
実験手順
A mixture of 1,4-dichlorobenzo[g]phthalazine (9.23 mmol) and n-butylamine (20 mL) was heated in an autoclave at 130° C. for 12 h. After cooling to room temperature, the excess of n-butyl amine was evaporated to dryness under vacuum. When the residue was treated with acetone (100 mL) a yellow solid was formed. After being filtered off and dried it afforded 1.87 g (55% yield) of 1,4-bis(n-butylamino)benzo[g]phthalazine monohydrochloride. m.p. 195°-197° C.