Dibenzylphosphate → Silver(1+) dibenzyl phosphate

HRID 864952ノート

反応式

HRID 864952 の反応式
[P:1]([O-:19])([O:11][CH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)([O:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)=[O:2].C(=O)([O-])[O-].[Ag+2:24]>C(#N)C.O.[Al]>[P:1]([O-:19])([O:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)([O:11][CH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)=[O:2].[Ag+:24]

参加物

6

反応物 2

HCID 4193600DibenzylphosphateHCID 178418647HCID 178418647、化合物

生成物 1

HCID 13248164Silver(1+) dibenzyl phosphate

試薬・触媒・溶媒 3

HCID 962Water溶媒HCID 6342Acetonitrile溶媒HCID 5359268Aluminum溶媒

実験手順

Dibenzyl phosphate (10 mmole, 2.78 g) is dissolved in a mixture of acetonitrile (20 ml) and water (10 ml). Silver carbonate (10 mmole, 2.76 g) is added, and the mixture is stirred at room temperature in the dark (wrapped in aluminum foil) for 2 hours. Excess of silver carbonate is removed by filtration. The solution is evaporated to dryness, and dried over P2O5 in the dark to constant weight (2 days). Yield of silver dibenzoyl phosphate is 3.61 g.

後処理

  1. customExcess of silver carbonate is removed by filtration
  2. customThe solution is evaporated to dryness
  3. dry with materialdried over P2O5 in the dark to constant weight (2 days)

出典と根拠

ORDレコード
ord-39b55e4f9ff449309a8e74ffe687fd81
出典データセット
uspto-grants-1996_10
特許番号
US05565439

反応ノート

読み込み中…