Water → Bisphenol E

HRID 866722

反応式

HRID 866722 の反応式
C(C1C=[C:7]([CH2:16][CH2:17][C:18]2[CH:23]=[C:22](C(C)(C)C)[C:21]([OH:28])=[C:20](C(C)(C)C)[CH:19]=2)[CH:8]=[C:9]([C:12]([CH3:15])(C)C)C=1O)(C)(C)C.[CH2:33]1C2C(=CC=CC=2)CCC1.[OH2:43]>C1(C)C=CC(S(O)(=O)=O)=CC=1>[CH3:33][CH:17]([C:18]1[CH:19]=[CH:20][C:21]([OH:28])=[CH:22][CH:23]=1)[C:16]1[CH:7]=[CH:8][C:9]([OH:43])=[CH:12][CH:15]=1

参加物

5

反応物 3

HCID 962WaterHCID 8404TetralinHCID 1648474,4'-(1,2-Ethanediyl)bis(2,6-bis(1,1-dimethylethyl)phenol

生成物 1

HCID 608116Bisphenol E収率 97%

試薬・触媒・溶媒 1

HCID 6101p-Toluenesulfonic acid溶媒

実験手順

A solution of 5.0 grams (0.011 mole) of 1,2-bis(3,5-di-t-butyl-4-hydroxyphenyl)ethane dissolved in 30 milliliters of tetralin containing 0.2 gram (0.0012 mole) of p-toluensulfonic acid was heated to reflux for a total of 3 hours. The reaction mixture was cooled and poured into 50 milliliters of water. The precipitated solid was collected by suction filtration and recrystallized from ethanol to yield 2.3 grams (97 percent) of bisphenol E, melting point 199°-200° C.

後処理

  1. temperaturewas heated
  2. temperatureto reflux for a total of 3 hours
  3. temperatureThe reaction mixture was cooled
  4. filtrationThe precipitated solid was collected by suction filtration
  5. customrecrystallized from ethanol

出典と根拠

ORDレコード
ord-9f1db7b4ffdc4dc9b504e7f12c195db1
出典データセット
uspto-grants-1978_07
特許番号
US04101391

関連ノート

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