Allyl phenyl ether → HCID 14328878、化合物

HRID 867959

反応式

HRID 867959 の反応式
[N:1]1([CH2:6][C:7]([C:11]2[CH:20]=[CH:19][C:18]3[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=3)[CH:12]=2)=[N+:8]([O-:10])[CH3:9])[CH:5]=[CH:4][N:3]=[CH:2]1.[CH2:21]([O:24][C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1)[CH:22]=[CH2:23]>C1(C)C=CC=CC=1>[N:1]1([CH2:6][C:7]2([C:11]3[CH:20]=[CH:19][C:18]4[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=4)[CH:12]=3)[CH2:23][CH:22]([CH2:21][O:24][C:25]3[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=3)[O:10][N:8]2[CH3:9])[CH:5]=[CH:4][N:3]=[CH:2]1

参加物

4

反応物 2

HCID 74458Allyl phenyl etherHCID 867424722-(1H-Imidazol-1-yl)-N-methyl-1-(2-naphthalenyl)ethanimine N-oxide

生成物 1

HCID 14328878HCID 14328878、化合物

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

A mixture of compound 2 (9.0 g, 0.034 mol) and phenyl allyl ether (6.98 ml, 0.051 mol) in 200 ml of toluene is refluxed for 48 hours, cooled and evaporated under vacuum. The semisolid that remained (7.30 g, 54%) is crystallized from ether and recrystallized from ethyl acetate to give tan crystals. Yield: 2.4 g (18%); m.p. 176°-178° C. (Found: C, 74.96; H, 6.41; N, 10.40. C25H25N3O2 requires: C, 75.16; H, 6.31; N, 10.52).

後処理

  1. temperatureis refluxed for 48 hours
  2. temperaturecooled
  3. customevaporated under vacuum
  4. customis crystallized from ether
  5. customrecrystallized from ethyl acetate
  6. customto give tan crystals

出典と根拠

ORDレコード
ord-40739d68791d434b838e2b7febef88e8
出典データセット
uspto-grants-1988_10
特許番号
US04777263

関連ノート

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