2,6-Dimethoxyphenol → HCID 14886366、化合物

HRID 868505ノート

反応式

HRID 868505 の反応式
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][CH:6]=[C:5]([O:9][CH3:10])[C:4]=1[OH:11].C1(=O)O[CH2:15][CH2:14][O:13]1.C(=O)([O-])[O-].[K+].[K+]>C1(C)C=CC=CC=1>[CH3:10][O:9][C:5]1[CH:6]=[CH:7][CH:8]=[C:3]([O:2][CH3:1])[C:4]=1[O:11][CH:14]([OH:13])[CH3:15]

参加物

5

反応物 3

HCID 70412,6-DimethoxyphenolHCID 7303Ethylene carbonateHCID 11430Potassium Carbonate

生成物 1

HCID 14886366HCID 14886366、化合物収率 100.7%

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

実験手順

A mixture of 6.0 g of 2,6-dimethoxyphenol, 6.8 g of ethylene carbonate and 5.4 g of potassium carbonate in 40 ml of toluene was refluxed for 17 hours. After cooling, toluene solution was separated, dried (Na2SO4) and solvent was evaporated. 7.77 g of desired compound was obtained.

後処理

  1. temperaturewas refluxed for 17 hours
  2. temperatureAfter cooling
  3. customtoluene solution was separated
  4. dry with materialdried (Na2SO4) and solvent
  5. customwas evaporated

出典と根拠

ORDレコード
ord-6f57dac6ec1f4290a78e514474cafdc2
出典データセット
uspto-grants-1988_10
特許番号
US04780462

反応ノート

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