Peracetic Acid → (6-Methyl-7-oxabicyclo[4.1.0]hept-3-yl)methanol

HRID 872426

反応式

HRID 872426 の反応式
[CH3:1][C:2]1[CH2:7][CH2:6][CH:5]([CH2:8][OH:9])[CH2:4][CH:3]=1.C(OO)(=[O:12])C>C(OCC)(=O)C>[CH3:1][C:2]12[O:12][CH:7]1[CH2:6][CH:5]([CH2:8][OH:9])[CH2:4][CH2:3]2

参加物

4

反応物 2

HCID 6585Peracetic AcidHCID 5646723-Cyclohexene-1-methanol, 4-methyl-

生成物 1

HCID 86623394(6-Methyl-7-oxabicyclo[4.1.0]hept-3-yl)methanol収率 95%

試薬・触媒・溶媒 1

HCID 8857Ethyl Acetate溶媒

実験手順

Epoxidation of 12.6 g (0.1 mol) of (4-methylcyclohex-3-enyl)methanol was performed with a 5 percent by weight solution of peroxyacetic acid in ethyl acetate at 65° C. The epoxidized product was purified by distillation and thereby yielded 12 g of (6-methyl-7-oxabicyclo[4.1.0]hept-3-yl)methanol with a purity of 98%.

後処理

  1. distillationThe epoxidized product was purified by distillation

出典と根拠

ORDレコード
ord-31a9f14e942a47a2a60663b414812bce
出典データセット
uspto-grants-2015_03
特許番号
US08975349B2

関連ノート

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