Thionyl Chloride → HCID 86615557、化合物
反応式
[N+:1]([C:4]1[CH:5]=[C:6]([CH:10]=[CH:11][C:12]=1[S:13][C:14]1[CH:19]=[CH:18][C:17]([NH:20][C:21]([O:23][CH2:24][C:25]([Cl:28])([Cl:27])[Cl:26])=[O:22])=[CH:16][CH:15]=1)[C:7](O)=[O:8])([O-:3])=[O:2].S(Cl)([Cl:31])=O>CN(C)C=O>[Cl:26][C:25]([Cl:28])([Cl:27])[CH2:24][O:23][C:21](=[O:22])[NH:20][C:17]1[CH:18]=[CH:19][C:14]([S:13][C:12]2[CH:11]=[CH:10][C:6]([C:7]([Cl:31])=[O:8])=[CH:5][C:4]=2[N+:1]([O-:3])=[O:2])=[CH:15][CH:16]=1参加物
4
実験手順
The product from Example 84a (2.0 g, 42.9 mmol) in thionyl chloride (10 mL) containing 1 drop of dimethylformamide and was heated to reflux for 3 hours. Cooled and concentrated under vacuum and dried under high vacuum overnight. The title compound was used without further purification.
後処理
- temperaturewas heated
- temperature