Methyl chloroformate → methyl N-methyl-N-(4-nitrophenyl)carbamate
反応式
[CH3:1][NH:2][C:3]1[CH:8]=[CH:7][C:6]([N+:9]([O-:11])=[O:10])=[CH:5][CH:4]=1.Cl[C:13]([O:15][CH3:16])=[O:14]>CO>[CH3:1][N:2]([C:3]1[CH:4]=[CH:5][C:6]([N+:9]([O-:11])=[O:10])=[CH:7][CH:8]=1)[C:13](=[O:14])[O:15][CH3:16]参加物
4
実験手順
The title compound was prepared from N-methyl-4-nitroaniline and methyl chloroformate according to Method Y and was isolated as a pale yellow solid (84%) after trituration in cold MeOH. δH (DMSO-d6) 8.22 (2H, d, J 9.3 Hz), 7.64 (2H, d, J 9.3 Hz), 3.70 (3H, s), 3.32 (3H, s).
出典と根拠
- ORDレコード
- ord-29310bcaca1442a0a8380884526ce804
- 出典データセット
- uspto-grants-2012_08
- 特許番号
- US08242116B2
反応ノート
読み込み中…