Allyl bromide → N,N-diallyl-4,4'-dinitro-2-biphenylamine
反応式
[N+:1]([C:4]1[CH:5]=[C:6]([NH2:19])[C:7]([C:10]2[CH:15]=[CH:14][C:13]([N+:16]([O-:18])=[O:17])=[CH:12][CH:11]=2)=[CH:8][CH:9]=1)([O-:3])=[O:2].[CH2:20](Br)[CH:21]=[CH2:22].C(=O)([O-])[O-].[K+].[K+].CN1C(=O)[CH2:34][CH2:33][CH2:32]1>>[CH2:20]([N:19]([CH2:34][CH:33]=[CH2:32])[C:6]1[C:7]([C:10]2[CH:11]=[CH:12][C:13]([N+:16]([O-:18])=[O:17])=[CH:14][CH:15]=2)=[CH:8][CH:9]=[C:4]([N+:1]([O-:3])=[O:2])[CH:5]=1)[CH:21]=[CH2:22]参加物
5
実験手順
A mixture of 4,4′-dinitro-2-biphenylamine (10.0 g), allyl bromide (20 mL), potassium carbonate (16 g) and NMP (100 mL) was heated to 90–95° C. for 90 hr. The mixture was extracted with tetrahydrofuran (THF)-ethyl acetate-water and purified by crystallization from ethyl acetate to give N,N-diallyl-4,4′-dinitro-2-biphenylamine (7.0 g).