(2-Aminobenzo[d]thiazol-6-yl)methanol → 2-Aminobenzo[d]thiazole-6-carbaldehyde

HRID 892332ノート

反応式

HRID 892332 の反応式
[NH2:1][C:2]1[S:3][C:4]2[CH:10]=[C:9]([CH2:11][OH:12])[CH:8]=[CH:7][C:5]=2[N:6]=1>C1COCC1.[O-2].[Mn+4].[O-2]>[NH2:1][C:2]1[S:3][C:4]2[CH:10]=[C:9]([CH:11]=[O:12])[CH:8]=[CH:7][C:5]=2[N:6]=1

参加物

4

反応物 1

HCID 13821540(2-Aminobenzo[d]thiazol-6-yl)methanol

生成物 1

HCID 138215412-Aminobenzo[d]thiazole-6-carbaldehyde

試薬・触媒・溶媒 2

HCID 178418406HCID 178418406、化合物触媒HCID 8028Tetrahydrofuran溶媒

実験手順

110.5 g (0.613 mol) of 1a are stirred in 200 ml of THF with 319.8 g (3.678 mol) of manganese (IV) oxide at room temperature for 3 days. The reaction mixture is filtered, the residue on the filter is washed with THF, and the filtrate is evaporated in vacuo.

後処理

  1. filtrationThe reaction mixture is filtered
  2. washthe residue on the filter is washed with THF
  3. customthe filtrate is evaporated in vacuo

出典と根拠

ORDレコード
ord-ca63e8c4dee84989bb31bff71d484377
出典データセット
uspto-grants-1992_06
特許番号
USRE033948

反応ノート

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