Triphenyltin Chloride → Triphenylstannane

HRID 892674

反応式

HRID 892674 の反応式
[H-].[H-].[H-].[H-].[Li+].[Al+3].[C:7]1([Sn:13](Cl)([C:20]2[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=2)[C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1>CCOCC>[C:20]1([SnH:13]([C:7]2[CH:8]=[CH:9][CH:10]=[CH:11][CH:12]=2)[C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=1

参加物

4

反応物 2

HCID 12540Triphenyltin ChlorideHCID 21226445Aluminium lithium hydride

生成物 1

HCID 6460Triphenylstannane

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

Triphenyl tin hydride was prepared as follows: a 4-neck flask equipped with magnetic stirring was charged with 600 ml of ether and 3.1 g (81 mmol) of LiAlH4 and cooled to 0° (ice+salt bath). 62.6 G (0.16 mol) of triphenyl tin chloride were added by means of a dropping funnel adapted for powder introduction. No exothermic reaction was observed. The mixture was allowed to warm up to room temperature and stirred for 1 h. It was then poured on ice, extracted with ether, washed 3 times with water, dried and concentrated. The raw product thus obtained (56.8 g) was used as such in the synthesis described above.

後処理

  1. customa 4-neck flask equipped
  2. temperaturecooled to 0° (ice+salt bath)
  3. customNo exothermic reaction
  4. stirringstirred for 1 h
  5. additionIt was then poured on ice
  6. extractionextracted with ether
  7. washwashed 3 times with water
  8. customdried
  9. concentrationconcentrated

出典と根拠

ORDレコード
ord-ee02ebcfd82d4b7994b1158c6e16d6a0
出典データセット
uspto-grants-1992_06
特許番号
US05118865

関連ノート

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