Sodium Hydroxide → Phenoxyacetylmethylenetriphenylphosphorane

HRID 893894ノート

反応式

HRID 893894 の反応式
[Cl-].[O:2]([CH2:9][C:10]([CH2:12][P+:13]([C:26]1[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=1)([C:20]1[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1)[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)=[O:11])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[OH-].[Na+]>O>[O:2]([CH2:9][C:10]([CH:12]=[P:13]([C:26]1[CH:27]=[CH:28][CH:29]=[CH:30][CH:31]=1)([C:20]1[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=1)[C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)=[O:11])[C:3]1[CH:4]=[CH:5][CH:6]=[CH:7][CH:8]=1

参加物

4

反応物 2

HCID 14798Sodium HydroxideHCID 20516787Phenoxyacetylmethyltriphenylphosphonium Chloride

生成物 1

HCID 11015099Phenoxyacetylmethylenetriphenylphosphorane

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

Phenoxyacetylmethyltriphenylphosphonium chloride (10 g, 22.40 mmol) was suspended in 250 ml water with a few crystals of phenolphthalien added as an indicator. Sodium hydroxide (5%) was added dropwise until the vigorously stirred mixture turned pink. The white solid was collected, washed with water, and dried in a desicator, weight 9 g (98%); mp 127-128.5; ir (KBr, cm-1) 1595, 1580, 1540, 1480, 1435, 1400, 1225, 1105, 1045, 870; nmr (DCCl3, ppm) 7.90-6.90 (m, 21H), 4.53 (s, 2H).

後処理

  1. additionadded as an indicator
  2. customThe white solid was collected
  3. washwashed with water
  4. customdried in a desicator, weight 9 g (98%)

出典と根拠

ORDレコード
ord-c392b28df73c44a98ce651242f37ba1b
出典データセット
uspto-grants-1981_08
特許番号
US04282149

反応ノート

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