Hydrochloric Acid → 4-Butylbenzoyl chloride

HRID 894875ノート

反応式

HRID 894875 の反応式
[CH2:1]([C:5]1[CH:13]=[CH:12][C:8]([C:9](O)=[O:10])=[CH:7][CH:6]=1)[CH2:2][CH2:3][CH3:4].S(Cl)([Cl:16])=O.Cl.S(=O)=O>C1(C)C=CC=CC=1>[CH2:1]([C:5]1[CH:13]=[CH:12][C:8]([C:9]([Cl:16])=[O:10])=[CH:7][CH:6]=1)[CH2:2][CH2:3][CH3:4]

参加物

6

反応物 4

HCID 313Hydrochloric AcidHCID 1119Sulfur DioxideHCID 24386Thionyl Chloride2 回HCID 886314-Butylbenzoic acid

生成物 1

HCID 1200494-Butylbenzoyl chloride

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒2 回

実験手順

A mixture of 1.1 g. of p-n-butyl benzoic acid, 2.5 g. of thionylchloride, 5 ml. of toluene and a small amount of zeolite was refluxed for about 4 hours to react them. After the reaction, excess of thionylchloride, dissolved hydrogen-chloride gas, sulfur dioxide gas, and toluene were vaporized to remove them by a rotary evaporator. A crude p-n-butyl benzoylchloride was obtained as a residue. On the other hand, 1.1 g. of 2,3-dichloroaniline was dissolved in 10 ml. of acetone and 1.3 g. of potassium carbonate was gradually added with stirring to suspend it.

後処理

  1. additionA mixture of 1.1 g
  2. customto react them
  3. customAfter the reaction
  4. customto remove them
  5. customby a rotary evaporator

出典と根拠

ORDレコード
ord-c5868ff78df2414dbb560cad61339864
出典データセット
uspto-grants-1981_08
特許番号
US04284813

反応ノート

読み込み中…