Styrene → alpha-Methyl-gamma-phenyl butyrolactone

HRID 894939ノート

反応式

HRID 894939 の反応式
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:9]([O-:13])(=[O:12])[CH2:10][CH3:11].[K+]>C(O)(=O)CC.[Mn+3]>[CH3:11][CH:10]1[CH2:1][CH:2]([C:3]2[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=2)[O:13][C:9]1=[O:12]

参加物

5

反応物 2

HCID 7501StyreneHCID 23663619Potassium propionate

生成物 1

HCID 11829963alpha-Methyl-gamma-phenyl butyrolactone収率 50%

試薬・触媒・溶媒 2

HCID 105130Manganese(3+)触媒HCID 1032Propionic Acid溶媒

実験手順

Styrene in an amount of 2.1 grams and 11.65 grams of manganic acetate, Mn(C2H3O2)3.2H2O, comprising two equivalents of Mn+3 based on titration value, were refluxed under nitrogen in 200 milliliters of propionic acid containing 20 grams of potassium propionate. In less than an hour, a 50% yield of alpha-methyl-gamma-phenyl butyrolactone was obtained.

後処理

  1. waitIn less than an hour

出典と根拠

ORDレコード
ord-529c1eb93976446e9adefbdeadd9c5c8
出典データセット
uspto-grants-1981_08
特許番号
US04285868

反応ノート

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