化工社化工社 化学情報印刷レポート · 研究参考用
Propanedinitrile, 2,2'-(1,4-cyclohexanediylidene)bis- → Tetracyanoquinodimethane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Propanedinitrile, 2,2'-(1,4-cyclohexanediylidene)bis- | HCID 73696 | — |
| 触媒 | HCID 178418406 | HCID 178418406 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | Tetracyanoquinodimethane | HCID 73697 | — |
反応手順
According to the procedure of Fatiadi Synthesis, 1976, 133, incorporated herein by reference, the 1,4-bis(dicyanomethylene)cyclohexane is allowed to react with manganese dioxide in refluxing (110° C.) toluene for ca. 15 minutes to provide TCNQ in ca. 60% yields.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04229364 |
| 出典データセット | uspto-grants-1980_10 |
| ORD ID | ord-366e9c2a0e504e51b09d96e9e5139ab7 |
| 出典メモ | uspto-grants-1980_10 |