Resorcinol → 1,3-Diisopropylbenzene

HRID 904008

反応式

HRID 904008 の反応式
C1(C=CC=C(O)C=1)O.[O-:9][OH:10].[O-]O.[CH:13]([C:16]1[CH:21]=[CH:20][CH:19]=[C:18]([CH:22]([CH3:24])[CH3:23])[CH:17]=1)([CH3:15])[CH3:14]>>[CH:22]([C:18]1[CH:19]=[CH:20][CH:21]=[C:16]([CH:13]([CH3:15])[CH3:14])[CH:17]=1)([CH3:24])[CH3:23].[O-:9][OH:10].[CH:22]([C:18]1[CH:19]=[CH:20][CH:21]=[C:16]([CH:13]([CH3:15])[CH3:14])[CH:17]=1)([CH3:24])[CH3:23]

参加物

4

反応物 2

HCID 5054ResorcinolHCID 53471113Hydroperoxide,1,1'-[1,3-phenylenebis(1-methylethylidene)]bis-

生成物 2

HCID 74501,3-DiisopropylbenzeneHCID 71436539m-Diisopropylbenzene monohydroperoxide

実験手順

A process for the preparation of resorcin comprising contacting impure meta-diisopropylbenzene dihydroperoxide obtained by liquid phase air oxidation of meta-diisopropylbenzene and/or meta-diisopropylbenzene monohydroperoxide, with a dispersion of a synthetic silica-alumina catalyst having a silica content of 60 to 95% by weight and a specific surface area of at least 100 m2 /g, under refluxing conditions in a mixed solvent of a ketone selected from the group consisting of acetone, methylethylketone and methylisobutyl ketone and an aromatic hydrocarbon selected from the group consisting of benzene, toluene, xylene and ethylbenzene containing 0.3 to 1.0% by weight of water based on the total starting mixture.

出典と根拠

ORDレコード
ord-c506e3dcd70942f48cdbbb923e2101a6
出典データセット
uspto-grants-1980_10
特許番号
US04229597

関連ノート

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