Butyl Formate → Dibutyl Oxalate

HRID 904933

反応式

HRID 904933 の反応式
[CH:1]([O:3][CH2:4][CH2:5][CH2:6][CH3:7])=[O:2]>C(O)CCC>[C:1]([O:3][CH2:4][CH2:5][CH2:6][CH3:7])(=[O:2])[C:1]([O:3][CH2:4][CH2:5][CH2:6][CH3:7])=[O:2]

参加物

3

反応物 1

HCID 11614Butyl Formate

生成物 1

HCID 16306Dibutyl Oxalate

試薬・触媒・溶媒 1

HCID 2631-Butanol溶媒

実験手順

Experiment was run in the same manner as in Example 4 except that the catalyst was replaced by 1.0 wt.% palladium-on-silicon-carbide. As the result, it was found that n-butyl formate was produced in a space time yield of 202 g./l.-catalyst.hr and small amounts of di-n-butyl oxalate and n-butanol were by-produced.

後処理

  1. customwas produced in a space time yield of 202 g

出典と根拠

ORDレコード
ord-57f0fcd15f7c4a6a815b1edb34f42b7d
出典データセット
uspto-grants-1983_12
特許番号
US04420633

関連ノート

読み込み中…