Ethanol → Diethyl Oxalate

HRID 904934

反応式

HRID 904934 の反応式
[C]=O.[H][H].N([O:7][CH2:8][CH3:9])=O.[CH:10]([O:12][CH2:13][CH3:14])=[O:11].[CH2:15]([OH:17])C>[Pd]>[C:15]([O:7][CH2:8][CH3:9])(=[O:17])[C:10]([O:12][CH2:13][CH3:14])=[O:11]

参加物

7

反応物 5

HCID 702EthanolHCID 8025Ethyl formateHCID 8026Ethyl NitriteHCID 178418361HCID 178418361、化合物HCID 178418416HCID 178418416、化合物

生成物 1

HCID 7268Diethyl Oxalate

試薬・触媒・溶媒 1

HCID 23938Palladium触媒

実験手順

In a tubular reactor, there was packed 10 ml. of a 0.5 wt.% palladium-on-alumina catalyst (manufactured by Nippon Engerhard Co., Ltd.), followed by introduction of a gaseous mixture consisting of 28.5% by volume of carbon monoxide, 4.5% by volume of hydrogen, 5.7% by volume of ethyl nitrite and 61.3% by volume of nitrogen at a rate of 40.0 l. per hour to subject the gaseous mixture to reaction at a reaction temperature of 120° C. under ambient pressure. According to a gas-chromatographic analysis of the reaction mixture, it was found that ethyl formate was produced in a space time yield of 235 g./l.-catalyst.hr and small amounts of diethyl oxalate and ethanol were by-produced.

後処理

  1. customIn a tubular reactor, there was packed
  2. waitper hour to subject
  3. customthe gaseous mixture to reaction at a reaction temperature of 120° C. under ambient pressure
  4. customwas produced in a space time yield of 235 g

出典と根拠

ORDレコード
ord-db63f6af83804701b175df29c244fbb5
出典データセット
uspto-grants-1983_12
特許番号
US04420633

関連ノート

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