Acetone → HCID 70525545、化合物

HRID 905092

反応式

HRID 905092 の反応式
[C:1]([C:6]1[CH:11]=[C:10]([C:12]([CH2:15][CH3:16])([CH3:14])[CH3:13])[CH:9]=[CH:8][C:7]=1O)([CH2:4][CH3:5])([CH3:3])[CH3:2].[CH2:18](Br)[CH:19]=[CH2:20].[C:22](=[O:25])([O-])[O-].[CH3:26][C:27]([CH3:29])=O>>[C:1]([C:6]1[CH:11]=[C:10]([C:12]([CH2:15][CH3:16])([CH3:14])[CH3:13])[CH:9]=[CH:8][C:7]=1[CH:20]=[CH:19][CH2:18][O:25][CH2:22][CH:26]=[CH:27][C:29]1[CH:8]=[CH:7][C:6]([C:1]([CH2:4][CH3:5])([CH3:3])[CH3:2])=[CH:11][C:10]=1[C:12]([CH2:15][CH3:16])([CH3:14])[CH3:13])([CH2:4][CH3:5])([CH3:3])[CH3:2]

参加物

5

反応物 4

HCID 180AcetoneHCID 7841Allyl bromideHCID 84552,4-Di-tert-pentylphenolHCID 19660Carbonate Ion

生成物 1

HCID 70525545HCID 70525545、化合物

実験手順

117.2 g of 2,4-di-t-amylphenol and 90.7 g of allylbromide was dissolved in 500 ml of acetone. Thereto was added 103.5 g of pottassium carbonate and refluxed in a water bath for 20 hours. Then reaction mixture was filtered under suction and filtration residue was rinsed with 100 ml of acetone, thereafter this was again mixed with the mother solution and then under reduced pressure acetone and excess allyl bromide was distilled out.

後処理

  1. temperaturerefluxed in a water bath for 20 hours
  2. customThen reaction mixture
  3. filtrationwas filtered under suction and filtration residue
  4. washwas rinsed with 100 ml of acetone
  5. additionthis was again mixed with the mother solution
  6. distillationunder reduced pressure acetone and excess allyl bromide was distilled out

出典と根拠

ORDレコード
ord-6ce65696a38043df969eb3d936abe02e
出典データセット
uspto-grants-1983_12
特許番号
US04421846

関連ノート

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