2-Nitrodiphenylamine → N-Phenyl-o-phenylenediamine

HRID 909847

反応式

HRID 909847 の反応式
[CH:1]1[CH:6]=[CH:5][C:4]([NH:7][C:8]2[C:13]([N+:14]([O-])=O)=[CH:12][CH:11]=[CH:10][CH:9]=2)=[CH:3][CH:2]=1.[H][H]>[Pd].C(O)C>[C:4]1([NH:7][C:8]2[C:13]([NH2:14])=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:3]=[CH:2][CH:1]=[CH:6][CH:5]=1

参加物

5

反応物 2

HCID 84072-NitrodiphenylamineHCID 178418361HCID 178418361、化合物

生成物 1

HCID 68297N-Phenyl-o-phenylenediamine

試薬・触媒・溶媒 2

HCID 23938Palladium触媒HCID 702Ethanol溶媒

実験手順

To a pressure reaction bottle was added 10 g 2-nitrodiphenylamine, 0.5 g 5% palladium on carbon and 100 ml 95% ethanol. The mixture was hydrogenated at 22 C and 40 psi hydrogen for 2 hours. Following filtration through celite and solvent removal, an oil was obtained that crystallized on standing.

後処理

  1. customTo a pressure reaction bottle
  2. filtrationfiltration through celite and
  3. customsolvent removal
  4. customan oil was obtained
  5. customthat crystallized

出典と根拠

ORDレコード
ord-24780042d67c4157a0498086f68596e6
出典データセット
uspto-grants-2011_09
特許番号
US08018639B2

関連ノート

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