1-Octanol → Octyl Acetate

HRID 916914

反応式

HRID 916914 の反応式
F[B-](F)(F)F.C(=O)([O-])[O-].[Na+].[Na+].[CH2:12]([OH:20])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19].[C:21](OC=C)(=[O:23])[CH3:22].C(OCCCCCCCC)=C>C1(C)C=CC=CC=1>[C:21]([O:20][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH3:19])(=[O:23])[CH3:22]

参加物

7

反応物 5

HCID 9571-OctanolHCID 7904Vinyl AcetateHCID 10340Sodium CarbonateHCID 26255TetrafluoroborateHCID 702491-(Vinyloxy)octane

生成物 1

HCID 8164Octyl Acetate

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒

反応条件

温度
100 °C

実験手順

To a mixture of bis(1,5-cyclooctadiene)iridium tetrafluoroborate [Ir(cod)2]+BF4− (0.01 mmol) and sodium carbonate (0.6 mmol) in toluene (1.0 ml), 1-octanol (130 mg, 1 mmol) and vinyl acetate (2 mmol) were added, followed by stirring at 100° C. in an atmosphere of argon gas for 2 hours. The reaction mixture was analyzed by gas chromatography to find that 1-octyl vinyl ether and octyl acetate were produced in yields of 70% and 2%, respectively, with a conversion from 1-octanol of 72%.

後処理

  1. additionwere added

出典と根拠

ORDレコード
ord-ec7e3262b7b24ff7afd4a77435999bc8
出典データセット
uspto-grants-2007_09
特許番号
US07271297B2

関連ノート

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