Styrene → HCID 68149203、化合物

HRID 917936

反応式

HRID 917936 の反応式
[CH3:1][O:2][C:3](=[O:8])[C:4]([C:6]#[N:7])=[CH2:5].[CH2:9]=[CH:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1>>[CH3:1][O:2][C:3](=[O:8])[C:4]([C:6]#[N:7])=[CH2:5].[CH2:9]=[CH:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1

参加物

3

反応物 2

HCID 7501StyreneHCID 8711Methyl cyanoacrylate

生成物 1

HCID 68149203HCID 68149203、化合物

反応条件

温度
65 °C

実験手順

A mixture of monomeric methyl-2-cyanoacrylate (16.0 g.), styrene (4.0 g), and 500 ml petroleum ether having a boiling range of 80° - 110°C. was added to a 1000 ml., 4-neck flask. The mixture was stirred and flushed with dry nitrogen while the temperature was slowly raised to 65°C. to complete the dissolution process. After this azobis-(isobutyronitrile) (0.10 g) was added and stirring ceased. The reaction mixture was held at 80°C. for 2 to 3 hours and the copolymer precipitated. The precipitate was stirred to suspend the precipitated copolymer and then the copolymer was collected on a suction funnel and dried at 60°C. under vacuum. The dried copolymer had a reduced viscosity of 1.48 (0.4 g in 100 ml. dimethyl formamide).

後処理

  1. additionwas added to a 1000 ml
  2. customflushed with dry nitrogen while the temperature
  3. additionAfter this azobis-(isobutyronitrile) (0.10 g) was added
  4. stirringstirring
  5. customthe copolymer precipitated
  6. stirringThe precipitate was stirred
  7. customthe copolymer was collected on a suction funnel
  8. customdried at 60°C. under vacuum

出典と根拠

ORDレコード
ord-0cb550eb5c204e9cafcf37641cb6e121
出典データセット
uspto-grants-1976_07
特許番号
US03968186

関連ノート

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