Acetic Acid → 4-((tert-Butyldimethylsilyl)oxy)benzene-1,2-diamine
反応式
[Si:1]([O:8][C:9]1[CH:14]=[CH:13][C:12]([NH2:15])=[C:11]([N+:16]([O-])=O)[CH:10]=1)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2].C(O)(=O)C>CCO.[Fe]>[Si:1]([O:8][C:9]1[CH:10]=[C:11]([NH2:16])[C:12]([NH2:15])=[CH:13][CH:14]=1)([C:4]([CH3:7])([CH3:6])[CH3:5])([CH3:3])[CH3:2]参加物
5
実験手順
The mixture of 4-(tert-butyldimethylsilyloxy)-2-nitrobenzenamine (0.5 g, 1.9 mmol), Fe powder (1.1 g, 19 mmol) and acetic acid (1.0 mL, 18 mmol) in EtOH (10 mL) was stirred at reflux for 4 hrs. The mixture was filtered through celite pad and the filtrate was concentrated.
後処理
- temperatureat reflux for 4 hrs
- filtrationThe mixture was filtered through celite pad
- concentrationthe filtrate was concentrated
出典と根拠
- ORDレコード
- ord-64301a4e86764faaa072ab461b72ee38
- 出典データセット
- uspto-grants-2016_03
- 特許番号
- US09273046B2
反応ノート
読み込み中…