HCID 12970067、化合物 → 2,4-Dipropylresorcinol
反応式
[CH2:1]([C:4]1[C:10]([OH:11])=[CH:9][CH:8]=[C:7]([CH2:12][CH:13]=[CH2:14])[C:5]=1[OH:6])[CH:2]=[CH2:3]>CO.[Pd]>[CH2:1]([C:4]1[C:5]([OH:6])=[C:7]([CH2:12][CH2:13][CH3:14])[CH:8]=[CH:9][C:10]=1[OH:11])[CH2:2][CH3:3]参加物
4
実験手順
The product 2,6-bis-allylresorcinol (33.5 gm) was dissolved in methanol and hydrogenated under H2 Pressure (initial pressure 45 psig) over 10% Pd on carbon (300 mg). The reaction mixture was filtered through celite and reduced i. vac. The crude oil was flushed through a short SiO2 gel column eluting with ethyl ether. The resulting oil was purified by crystallization from hexanes:ether.
後処理
- filtrationThe reaction mixture was filtered through celite
- customThe crude oil was flushed through a short SiO2 gel column
- washeluting with ethyl ether
- customThe resulting oil was purified by crystallization from hexanes
出典と根拠
- ORDレコード
- ord-2bfb2671409546e88e8771b6b2fea5b7
- 出典データセット
- uspto-grants-2006_08
- 特許番号
- US07091230B2
反応ノート
読み込み中…