Triisopropyl phosphite → Diethyl 5-[di(propan-2-yloxy)phosphorylmethyl]-3-formamidonon-4-enedioate

反応式

[CH:1](=[O:2])[NH:3][CH:4]([CH2:5][C:6](=[O:7])[O:8][CH2:9][CH3:10])[CH:11]=[C:12]([CH2:13][CH2:14][CH2:15][C:16](=[O:17])[O:18][CH2:19][CH3:20])[CH2:21][Br:22].[CH:23]([CH3:24])([CH3:25])[O:26][P:27]([O:28][CH:29]([CH3:30])[CH3:31])[O:32][CH:33]([CH3:34])[CH3:35]>>[CH:1](=[O:2])[NH:3][CH:4]([CH2:5][C:6](=[O:7])[O:8][CH2:9][CH3:10])[CH:11]=[C:12]([CH2:13][CH2:14][CH2:15][C:16](=[O:17])[O:18][CH2:19][CH3:20])[CH2:21][P:27]([O:26][CH:23]([CH3:24])[CH3:25])([O:28][CH:29]([CH3:30])[CH3:31])=[O:32]

参加物

反応物 2

HCID 8304Triisopropyl phosphite

HCID 54128616Diethyl 2-formylamino-4-bromomethyl-hept-3-ene-1,7-dicarboxylate

生成物 1

HCID 54024169Diethyl 5-[di(propan-2-yloxy)phosphorylmethyl]-3-formamidonon-4-enedioate

出典と根拠

ORDレコード: ord-7c9ca5063c3b4052955ae5c911e6e3ea
出典データセット: Training data from https://doi.org/10.1039/C8SC04228D (2/10)
DOI: 10.1039/C8SC04228D

反応ノート

読み込み中…