p-Methoxybenzophenonoxime → 1-(4-Methoxyphenyl)-1-phenylmethanamine

HRID 962710

反応式

HRID 962710 の反応式
[CH3:1][O:2][C:3]1[CH:17]=[CH:16][C:6]([C:7](=[N:14]O)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)=[CH:5][CH:4]=1.C([O-])(=O)C.[NH4+].C([BH3-])#N.[Na+]>[Cl-].[Cl-].[Cl-].[Ti+3]>[CH3:1][O:2][C:3]1[CH:17]=[CH:16][C:6]([CH:7]([NH2:14])[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)=[CH:5][CH:4]=1

参加物

5

反応物 3

HCID 185567p-MethoxybenzophenonoximeHCID 517165Ammonium AcetateHCID 5003444Sodium cyanoborohydride

生成物 1

HCID 3500411-(4-Methoxyphenyl)-1-phenylmethanamine収率 76.9%

試薬・触媒・溶媒 1

HCID 10313229titanium(III) trichloride触媒

実験手順

Following a procedure similar to that described in Preparation 12, but using 9.4 g of 4-methoxybenzophenone oxime, 33.9 g of ammonium acetate, 7.46 g of sodium cyanoborohydride, and 79 ml of a 17-19% by volume aqueous solution of titanium trichloride, 6.78 g of the title compound were obtained as an oily substance.

後処理

  1. customthat described in Preparation 12

出典と根拠

ORDレコード
ord-ad22e48ef3424386b703fcae5d7c35b9
出典データセット
uspto-grants-1998_06
特許番号
US05760025

関連ノート

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