1,3-Dibromobenzene → (3-Bromophenyl)(tributyl)silane

反応式

Br[C:2]1[CH:7]=[CH:6][CH:5]=[C:4]([Br:8])[CH:3]=1.Cl[Si:10]([CH2:19][CH2:20][CH2:21][CH3:22])([CH2:15][CH2:16][CH2:17][CH3:18])[CH2:11][CH2:12][CH2:13][CH3:14]>>[Br:8][C:4]1[CH:5]=[CH:6][CH:7]=[C:2]([Si:10]([CH2:15][CH2:16][CH2:17][CH3:18])([CH2:19][CH2:20][CH2:21][CH3:22])[CH2:11][CH2:12][CH2:13][CH3:14])[CH:3]=1

参加物

反応物 2

HCID 79271,3-Dibromobenzene

HCID 70448Tributylchlorosilane

生成物 1

HCID 18913631(3-Bromophenyl)(tributyl)silane

実験手順

1-Bromo-3-tri-n-butylsilanyl-benzene is prepared in a manner analogous to the procedure described in examples 1 and 1a utilizing 1,3-dibromobenzene and chloro-tri-n-butylsilane as the ClSiR1R2R3 compound.

出典と根拠

ORDレコード: ord-ef7db5b7cea64cceb7e9c404e8f4c0f1
出典データセット: uspto-grants-1998_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05760267

反応ノート

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