2-Mesityl-3-nitropyridine → 2-Mesityl-3-pyridinamine

HRID 966014

反応式

HRID 966014 の反応式
[C:1]1([CH3:18])[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[C:9]1[C:14]([N+:15]([O-])=O)=[CH:13][CH:12]=[CH:11][N:10]=1>C(O)C.[H][H].[C].[Pd]>[C:1]1([CH3:18])[CH:6]=[C:5]([CH3:7])[CH:4]=[C:3]([CH3:8])[C:2]=1[C:9]1[C:14]([NH2:15])=[CH:13][CH:12]=[CH:11][N:10]=1

参加物

5

反応物 1

HCID 222494912-Mesityl-3-nitropyridine

生成物 1

HCID 167414262-Mesityl-3-pyridinamine収率 106.5%

試薬・触媒・溶媒 3

HCID 178418390HCID 178418390、化合物触媒HCID 702Ethanol溶媒HCID 178418361HCID 178418361、化合物溶媒

実験手順

Palladium-carbon (10%, 0.6 g) was added to a solution of 2-mesityl-3-nitropyridine (5.99 g, 23 mmol) in ethanol (120 mL), followed by stirring for one day in hydrogen atmospher. The mixture was filtered through Celite and evaporated, to give the title compound (5.2 g) as white crystals.

後処理

  1. filtrationThe mixture was filtered through Celite
  2. customevaporated

出典と根拠

ORDレコード
ord-c73ee1167547434ca4212285a5e42e77
出典データセット
uspto-grants-2005_10
特許番号
US06951865B2

関連ノート

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